Reactivity of phthalimide-N-oxyl : A kinetic study.

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Pronounced non-Arrhenius behaviour of hydrogen-abstractions from toluene and derivatives by phthalimide-N-oxyl radicals: a theoretical study.

Abstraction of hydrogen atoms by pthalimide-N-oxyl radicals is an important step in the N-hydroxyphthalimide catalyzed autoxidation of hydrocarbons. In this contribution, the temperature dependency of this reaction is evaluated by a detailed transition state theory based kinetic analysis for the case of toluene. Tunneling was found to play a very important role, enhancing the rate constant by a...

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ژورنال

عنوان ژورنال: Chemical and Pharmaceutical Bulletin

سال: 1987

ISSN: 0009-2363,1347-5223

DOI: 10.1248/cpb.35.1372