Reactivity of phthalimide-N-oxyl : A kinetic study.
نویسندگان
چکیده
منابع مشابه
Microencapsulation of Ethion by Interfacial Polymerization Utilizing Potassium Phthalimide-N-oxyl (PPINO) as a Promoter
متن کامل
Pronounced non-Arrhenius behaviour of hydrogen-abstractions from toluene and derivatives by phthalimide-N-oxyl radicals: a theoretical study.
Abstraction of hydrogen atoms by pthalimide-N-oxyl radicals is an important step in the N-hydroxyphthalimide catalyzed autoxidation of hydrocarbons. In this contribution, the temperature dependency of this reaction is evaluated by a detailed transition state theory based kinetic analysis for the case of toluene. Tunneling was found to play a very important role, enhancing the rate constant by a...
متن کاملN-(2-Ethylphenyl)phthalimide
In the title compound, C(16)H(13)NO(2), the phthalimide and benzene ring systems form a dihedral angle of 77.2 (1)°.
متن کاملN-(3,4-Difluorophenyl)phthalimide
In the title compound, C(14)H(7)F(2)NO(2), the phthalimide ring system is nearly planar [maximum atomic deviation = 0.028 (1) Å] and it is twisted with respect to the attached benzene ring, making a dihedral angle of 55.70 (6)°. Weak inter-molecular C-H⋯F hydrogen bonds are present in the crystal structure.
متن کاملN-(4-Methoxyphenyl)phthalimide
The phthalimide fused-ring system and the phenyl-ene ring in the title compound, C(15)H(11)NO(3), are inclined at an angle of 60.0 (1)°.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1987
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.35.1372